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Electrochemical Diazidation of Alkenes Catalyzed by Manganese Porphyrin Complexes with Second-Sphere Hydrogen-Bond Donors

https://doi.org/10.1021/acscatal.2c05186

Novaes, Luiz F.; Wang, Yi; Liu, Jinjian; Riart-Ferrer, Xavier; Cindy Lee, Wan-Chen; Fu, Niankai; Ho, Justin S.; Zhang, X. Peter; Lin, Song (November 2022, ACS Catalysis)

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Three-Component Chlorophosphinoylation of Alkenes via Anodically Coupled Electrolysis

https://doi.org/10.1055/s-0039-1689934

Lu, Lingxiang; Fu, Niankai; Lin, Song (May 2019, Synlett)

We report the development of an electrocatalytic protocol for the chlorophosphinoylation of simple alkenes. Driven by electricity and mediated by a Mn catalyst, the heterodifunctionalization reaction takes place with high efficiency and regioselectivity. Cyclic voltammetry data are consistent with a mechanistic scenario based on anodically coupled electrolysis in which the generation of two distinct radical intermediates occur simultaneously on the anode and are both mediated by the Mn catalyst.
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A general, electrocatalytic approach to the synthesis of vicinal diamines

https://doi.org/10.1038/s41596-018-0010-0

Fu, Niankai; Sauer, Gregory S.; Lin, Song (August 2018, Nature Protocols)

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Mn-Catalyzed Electrochemical Chloroalkylation of Alkenes

https://doi.org/10.1021/acscatal.8b03209

Fu, Niankai; Shen, Yifan; Allen, Anthony R.; Song, Lu; Ozaki, Atsushi; Lin, Song (November 2018, ACS Catalysis)

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Synthesis of Chlorotrifluoromethylated Pyrrolidines by Electrocatalytic Radical Ene-Yne Cyclization

https://doi.org/10.1002/chem.201802167

Ye, Ke-Yin; Song, Zhidong; Sauer, Gregory S.; Harenberg, Johannes H.; Fu, Niankai; Lin, Song (August 2018, Chemistry - A European Journal)

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Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO–N ₃ Charge-Transfer Complex

https://doi.org/10.1021/jacs.8b06744

Siu, Juno C.; Sauer, Gregory S.; Saha, Ambarneil; Macey, Reed L.; Fu, Niankai; Chauviré, Timothée; Lancaster, Kyle M.; Lin, Song (September 2018, Journal of the American Chemical Society)

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